Advanced search
Publication Cover
Phosphorus, Sulfur, and Silicon and the Related Elements Volume 123, 1997 - Issue 1
Submit an article Journal homepage
215
Views
2
CrossRef citations to date
0
Altmetric
Original Articles

THE KINETICS AND MECHANISM OF THE REACTION OF TRICOORDINATE PHOSPHORUS COMPOUNDS WITH SULFENATE ESTERS

C. Dennis Hall Department of Chemistry, King's College London, Strand, London, WC2R 2LS, UK
,
Bruce R. Tweedy Department of Chemistry, King's College London, Strand, London, WC2R 2LS, UK
&
Nicholas Lowther Department of Chemistry, King's College London, Strand, London, WC2R 2LS, UK
Pages 341-358 | Received 09 Mar 1997, Accepted 12 May 1997, Published online: 04 Oct 2006
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

The kinetics and mechanism of the reaction of tricoordinate phosphorus compounds, ArnP(OCH2CF3)3-n with arylsulfenate esters, ArSOCH2CF3, are reported. Product analysis, kinetic order, activation parameters, Hammett data and solvent effects are the criteria used to elucidate the two step mechanism involving arylthiophosphoranes as intermediates.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.