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Original Articles

Synthesis of a Stable Sulfenic Acid by Oxidation of a Thiol Bearing a Novel Bowl-type Substituent and Its Redox Reactions

Pages 325-326 | Published online: 17 Mar 2008
 

Abstract

A stable sulfenic acid bearing a novel bowl-type substituent was synthesized by direct oxidation of a thiol, and its structure was determined by X-ray crystallographic analysis. The redox reactions of a sulfenic acid to a thiol and to a sulfinic acid, for which only those of transient species have been reported so far, were also demonstrated conclusively.

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