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Original Articles

Stereospecific Transformations of Chiral Compounds Using Anchimeric Assistance of Arylthio and Arylseleno Group

Pages 355-356 | Published online: 30 Jul 2008
 

Abstract

A new chiral pool method is developed starting from readily available chiral oxiranes, the key step being the substitution reaction through the anchimeric assistance of the arylthio and arylseleno group. The overall transformation is the introduction of nucleopiles into the chiral carbon of the oxiranes with retention of the configuration.

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