Addition of α-phosphonate carbanions to (S)-sulfinimines 2 gives N-sulfinyl-β-aminophosphonates 3 with a high diastereoselectivity (up to 10:1). The major diastereomer of 3 (R=Ph) was converted into (+)-(R)-β-amino-β-phenylethanephosphonic acid 5.

KEY WORDS::

β-aminophosphonic acids
chiral sulfinimines
X-ray analysis

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