Nucleophilic and Electrophilic Additions to Silylated Ketenimines Generated from Imidothioesters.: Phosphorus, Sulfur, and Silicon and the Related Elements: Vol 120, No 1

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Abstract

The reactivity of stable silylated N-phenyl ketenimines towards some nucleophilic (organometallics, alcohols, thiols) and electrophilic reagents (PhSCI) were studied. Imino-coumarines (via tandem nucleophilic-electrophilic additions with Peterson olefination) and new phenylthio- and silyl-substituted ketenimines have been prepared.

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Nucleophilic and Electrophilic Additions to Silylated Ketenimines Generated from Imidothioesters.

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Nucleophilic and Electrophilic Additions to Silylated Ketenimines Generated from Imidothioesters.

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