Structures and Reaction Mechanism of Novel Metal-Carbene Complexes Derived from Hypervalent Diazadiselenathiapentalenes: Phosphorus, Sulfur, and Silicon and the Related Elements: Vol 120, No 1

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Abstract

Novel metal-carbene complexes (4) with a metallapentalene framework have been obtained from hypervalent diazadiselenathiapentalenes (3) by treating with Pt(PPh₃)₄, Pd(PPh₃)₄ and RhCl(PPh₃)₃. X-Ray investigations revealed that the central hypervalent sulfur atom in 3 was substituted by a metal atom to form M-Se bonds in the resultant metallapentalene framework.

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Structures and Reaction Mechanism of Novel Metal-Carbene Complexes Derived from Hypervalent Diazadiselenathiapentalenes

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Structures and Reaction Mechanism of Novel Metal-Carbene Complexes Derived from Hypervalent Diazadiselenathiapentalenes

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