Stereospecific Redox Reaction Directed by a Sulfinyl Group: Phosphorus, Sulfur, and Silicon and the Related Elements: Vol 120, No 1

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Abstract

Stereochemistry of reductions of a pyridinium and quinoliniums with an asymmetric sulfinyl group has been studied. Dithionite and borohydride prefer the face characterized by a lone pair on sulfur atom. Dihydropyridine prefers the face characterized by a S-O bond.

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Stereospecific Redox Reaction Directed by a Sulfinyl Group

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Stereospecific Redox Reaction Directed by a Sulfinyl Group

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