(S)- and (R)-β-amino acid derivatives were synthesized by the asymmetric conjugate addition of ammonia and piperidazine to t-butyl (E)-2-[(R)- and (S)-p-tolylsulfinyl]cinnamates, respectively.

KEY WORDS::

CHIRAL VINYL SULFOXIDES
CONJUGATE ADDITION
β-AMINO ACID DERIVATIVES
(S)-CELACINNINE

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