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Original Articles

PHOSPHORYLATION OF 5-ARYLMETYLIDENE-1-MORPHOLINOCYCLOPENTENES

, , , , &
Pages 209-229 | Received 21 Feb 1998, Accepted 28 Apr 1998, Published online: 16 Feb 2007
 

Abstract

The phosphorylation reaction of 5–arylmethylidene–1–morpholinocyclopentenes with various phosphorus (III) and (V) halides was studied. It was shown that the enamines react with phosphorus (III) halides giving stable halo– and dihalophosphines which are key substances for further synthesis.

Hydrolysis of the phosphorylated enamines does not afford the expected phosphorylated ketones, decomposition being observed in acidic media.

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