PHOSPHINE- AND PHOSPHITE-SUBSTITUTED 3,3′-BI-INDOLIZINES- NEW ATROPISOMERIC LIGANDS

Angela Köckritz Institut für Angewandte Chemie Berlin-Adlershof, Rudower Chaussee 5, D-12484, Berlin, Germany

Helmut Sonnenschein Institut für Angewandte Chemie Berlin-Adlershof, Rudower Chaussee 5, D-12484, Berlin, Germany

Stefan Bischoff Institut für Angewandte Chemie Berlin-Adlershof, Rudower Chaussee 5, D-12484, Berlin, Germany

Fritz Theil Institut für Angewandte Chemie Berlin-Adlershof, Rudower Chaussee 5, D-12484, Berlin, Germany

Jörg Gloede Institut für Angewandte Chemie Berlin-Adlershof, Rudower Chaussee 5, D-12484, Berlin, Germany

Abstract

For the first time enantiomerically pure phosphine- or phosphite-substituted 1,1′-alkyl-3,3′-bi-indolizines were obtained. In situ prepared rhodium complexes of these compounds were tested in hydroformylation of styrene and methylstyrene.

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PHOSPHINE- AND PHOSPHITE-SUBSTITUTED 3,3′-BI-INDOLIZINES- NEW ATROPISOMERIC LIGANDS

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PHOSPHINE- AND PHOSPHITE-SUBSTITUTED 3,3′-BI-INDOLIZINES- NEW ATROPISOMERIC LIGANDS

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