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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 152, 1999 - Issue 1
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Original Articles

SYNTHESIS AND BIOLOGICAL ACTIVITY OF A RETINYL PHOSPHONIC ACID DERIVATIVE AN ANALOG OF RETINYL PHOSPHATE: HOMORETINYLPHOSPHONIC ACID

Mehrnaz Kamal Laboratoire de Chimie Biomoléculaire, Associé CNRS, Université Montpellier II cc073, Pl. E. Bataillon, 34095, Montpellier, Cedex 05, France
,
Jean-Yves Winum Laboratoire de Chimie Biomoléculaire, Associé CNRS, Université Montpellier II cc073, Pl. E. Bataillon, 34095, Montpellier, Cedex 05, France
,
Véronique Barragan Laboratoire de Chimie Biomoléculaire, Associé CNRS, Université Montpellier II cc073, Pl. E. Bataillon, 34095, Montpellier, Cedex 05, France
,
Alain Leydet Laboratoire de Chimie Biomoléculaire, Associé CNRS, Université Montpellier II cc073, Pl. E. Bataillon, 34095, Montpellier, Cedex 05, France
&
Jean-Louis Montero Laboratoire de Chimie Biomoléculaire, Associé CNRS, Université Montpellier II cc073, Pl. E. Bataillon, 34095, Montpellier, Cedex 05, France
Pages 241-256 | Received 28 Jan 1999, Accepted 26 Feb 1999, Published online: 24 Sep 2006
 
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Abstract

The synthesis of phosphonate isosteres or homologues of natural retinylphosphate was developed starting from carbonylated terpenes, through Abramov and Wittig-Horner reactions. Homoretinylphosphonic acid (HRP) was isolated and tested for its ability to be involved in the biosynthesis of membrane glycoconjugates.

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