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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 149, 1999 - Issue 1
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Original Articles

PHOTOSENSITIZED OXYGENATIONS OF DIMETHYL FLUORENYLIDENETRIBUTYL-AND TRIPHENYLPHOSPHORANYLI-DENESUCCINATE

Yasuhiko Kawamura Department of Chemical Science and Technology, Faculty of Engineering, The University of Tokushima, Minamijosanjima-cho, Tokushima, 770-8506, Japan
,
Yoshinori Sato Department of Chemical Science and Technology, Faculty of Engineering, The University of Tokushima, Minamijosanjima-cho, Tokushima, 770-8506, Japan
,
Masaya Arai Department of Chemical Science and Technology, Faculty of Engineering, The University of Tokushima, Minamijosanjima-cho, Tokushima, 770-8506, Japan
,
Tokunaru Horie Department of Chemical Science and Technology, Faculty of Engineering, The University of Tokushima, Minamijosanjima-cho, Tokushima, 770-8506, Japan
&
Masao Tsukayama Department of Chemical Science and Technology, Faculty of Engineering, The University of Tokushima, Minamijosanjima-cho, Tokushima, 770-8506, Japan
Pages 1-6 | Received 25 Jun 1998, Published online: 24 Sep 2006
 
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Abstract

Photosensitized oxygenation of extremely stable P-ylides, dimethyl fluorenylidenetributyl-and triphenylphosphoranylidenesuccinate, afforded dimethyl fluorenylideneoxalacetate in good yield, when 9-fluorenone was employed as a photosensitizer.

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