On the Reactions of Trithiophosphites with Alcohols in the Presence of Transition Metal Halides

Elvira S. Batyeva A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, Arbuzov str., 8, Kazan, Russia, 420088

Lidiya I. Kursheva A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, Arbuzov str., 8, Kazan, Russia, 420088

Liliya V. Frolova A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, Arbuzov str., 8, Kazan, Russia, 420088

Anatolyi M. Il'in A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, Arbuzov str., 8, Kazan, Russia, 420088

Rushaniya J. Valiullina A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, Arbuzov str., 8, Kazan, Russia, 420088

Sergey V. Zakharov A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, Arbuzov str., 8, Kazan, Russia, 420088

Abstract

Recently we have established that triphenyl- and trialkyltrithiophos-phites react with copper(1) halides with the formation of different typcs of occupies depending on substituents in the thioalkylgmup and on the conditions. Thesc complexes readily react with alcohols Rsulting in dialkylphosphorous acid [I]. We have assumed that the analogous phosphorylation of alcohols by (PhS), P and (AlkS)3P must be conducted in the presence of transition metal halides (CuCI, CuBr, CdCI₂, CdI₂, ZnC1₂, HgCl₂, HgBr₂) as well.

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On the Reactions of Trithiophosphites with Alcohols in the Presence of Transition Metal Halides

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On the Reactions of Trithiophosphites with Alcohols in the Presence of Transition Metal Halides

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