Intramolecular Rearrangements of α-Acylamino-Phosphites

F. I. Guseinov Department of Organic Chemistry, Kazan State Technological University, 420015, K. Marx str., 68, Kazan, Russia

R. N. Burangulova Department of Organic Chemistry, Kazan State Technological University, 420015, K. Marx str., 68, Kazan, Russia

G. U. Klimentova Department of Organic Chemistry, Kazan State Technological University, 420015, K. Marx str., 68, Kazan, Russia

Abstract

For the first time we have found out the regularity of rearrangements in a number of α-acylaminophosphites. Phosphites (1) transform to phosphonates (2) if there is a proton at nitrogen atom, in the case of alkyl substituent this rearrangement does not take place.

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Intramolecular Rearrangements of α-Acylamino-Phosphites

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Intramolecular Rearrangements of α-Acylamino-Phosphites

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