Synthesis and Coordination Chemistry of Novel Phosphiranes

Jürgen Liedtke Laboratory of Inorganic Chemistry, ETHZ, Universitätsstrasse 6, CH-8092, Zürich, Switzerland

Sandra Loss Laboratory of Inorganic Chemistry, ETHZ, Universitätsstrasse 6, CH-8092, Zürich, Switzerland

Hansjörg Grützmacher Laboratory of Inorganic Chemistry, ETHZ, Universitätsstrasse 6, CH-8092, Zürich, Switzerland

Abstract

Three-membered PC₂ heterocycles may find interesting applications in tansition metal catalysis but are intrinsically unstaMelll. We developed an efficient simple synthesis of a tricydic phosphirane 3 (BABAR-Phos) which is indefinitely stable in substance at room temperature and may be handled on air (Scheme 1).

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Synthesis and Coordination Chemistry of Novel Phosphiranes

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Synthesis and Coordination Chemistry of Novel Phosphiranes

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