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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 147, 1999 - Issue 1
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Original Articles

Chemo-and Stereoselectivity of Nucleophilic Substitution in Mixed Phosphorus-Carboxylic Anhydrides

Lucyna A. Woźniak Center of Molecular & Macromolecular Studies, Polish Academy of Sciences, Department of Bioorganic Chemistry, Sienkiewicza, 112, Łódź, POLAND
,
Arkadiusz Chworoś Center of Molecular & Macromolecular Studies, Polish Academy of Sciences, Department of Bioorganic Chemistry, Sienkiewicza, 112, Łódź, POLAND
&
Wojciech J. Stec Center of Molecular & Macromolecular Studies, Polish Academy of Sciences, Department of Bioorganic Chemistry, Sienkiewicza, 112, Łódź, POLAND
Page 435 | Published online: 23 Oct 2006
 
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Abstract

Miwed phosphorus-carboxylic anhydrides have demonstrated both acylating and phosphorylating properties.[1] Here we report the reactivity of O,O-diethyl(O-2,4,6-trimethylbenzoyl) phosphates (1), and O-methyl (O-2,4,6-trimetyIbenzoyl) dimethylphosphonates (2)with nucleophiles in the presence of different strong organic bases (DBU, DMAP).

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