Structure and Dynamical Behaviour of Bis(N-Diisopropoxy-Phosphorylthiobenzamido) Copper(II)

A. L. Kon'kin Kazan State University, Kremlevskaya Str. 18, Kazan, 420008, Russian Federation

V. G. Shtyrlin Kazan State University, Kremlevskaya Str. 18, Kazan, 420008, Russian Federation

N. G. Zabirov Kazan State University, Kremlevskaya Str. 18, Kazan, 420008, Russian Federation

I. A. Litvinov Kazan State University, Kremlevskaya Str. 18, Kazan, 420008, Russian Federation

A. T. Gubaidullin Kazan State University, Kremlevskaya Str. 18, Kazan, 420008, Russian Federation

R. R. Garipov Kazan State University, Kremlevskaya Str. 18, Kazan, 420008, Russian Federation

A. V. Aganov Kazan State University, Kremlevskaya Str. 18, Kazan, 420008, Russian Federation

A. V. Zakharov Kazan State University, Kremlevskaya Str. 18, Kazan, 420008, Russian Federation

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Abstract

Among the new compounds of N-(thio)phosphorylthiómides. the copper(II) complex with N-diisopropoxyphosphorylthiohenzamide (Cul. 2) exhibits series of unusual properties which have been extcnsively investigated in the present work. The X-ray structure of CuL₂ has been determined Crystals of CuL₂ are monoclinic. P2₁/c, a = 15.610, b = 11.880, and c = 18.320 Å, β = 106.74°. Z = 4. The CuL₂ complex has the cis-structure with Cu-S distances ranging from 2.238 to 2.253 Å and Cu-O distances being from 1.919 to 1.937 Å (Figure).

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Structure and Dynamical Behaviour of Bis(N-Diisopropoxy-Phosphorylthiobenzamido) Copper(II)

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Structure and Dynamical Behaviour of Bis(N-Diisopropoxy-Phosphorylthiobenzamido) Copper(II)

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