Stereoselective Reactions of Allylic Hydroxy Phosphonates

Abstract

The stereochemical outcome of the palladium catalyzed addition of nucleophiles to the carbonate derivative, the [3,3] rearrangement of the imidate and carbamate derivatives, and the epoxidation and cyclopropanation of hydroxy allylic phosphonates is presented.

Keywords::

• phosphonates
• stereoselective
• asymmetric
• cyclopropanation
• epoxidation