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Original Articles

New Carbon-Phosphorus Macrocycles

Pages 251-256 | Published online: 17 Mar 2008
 

Abstract

The synthesis of several phosphole and phosphinine-based macrocycles is described. The first ones are flexible as a result of the low inversion barrier of phosphorus. The mixture of isomers can be directly used in coordination chemistry. The second ones are not plagued by conformational problems and display strong π-acceptor properties.

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