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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 153, 1999 - Issue 1
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Original Articles

Generation and Reactivity of α-Phosphorylated Sulfur Stabilised Carbanions and Ylides; Selective Syntheses of α-Thiosubstituted Phosphonates

Mihaela Gulea
,
Patrice Marchand
,
Monique Saquet
,
Serge Masson
&
Noël Collignon
Pages 327-328 | Published online: 17 Mar 2008
 
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Abstract

An asymmetric synthesis of an α-mercapto-but-3-enyl phosphonate and the preparation of various α-phosphorylated unsaturated sulfides were respectively achieved via carbanion and ylide [2,3]-sigmatropic rearrangements.

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