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Integrated Ferroelectrics
An International Journal
Volume 122, 2010 - Issue 1
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Original Articles

Electrical Conduction Behaviour of CaCu3Ti4O12 Ceramics with Different Sintering Times

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Pages 108-113 | Received 13 Dec 2009, Accepted 14 Apr 2010, Published online: 20 Nov 2010
 

Abstract

Effect of sintering time on ac conduction has been investigated at different frequencies over a wide range of temperatures. Results have been discussed in the light of different conduction mechanisms. Variation of frequency exponent, ‘n’ (σ = A f n) with temperature has been studied. Owing to its variation with temperature, conduction behavior may be attributed to correlated barrier hoping (CBH) mechanism. Frequency exponent n, which is degree of correlation among charge carriers, found to increase with sintering time. Variation of activation energy with sintering time and frequency has also been studied in detail. Activation energy is observed to decrease with increase in both sintering time and frequency.

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