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Integrated Ferroelectrics
An International Journal
Volume 129, 2011 - Issue 1
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Original Articles

Modification of Rutile Nano-TiO2 Powders with Visible Light Photocatalytic Activity in Hydrogen or Nitrogen Atmosphere

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Pages 169-175 | Received 12 Jul 2010, Accepted 24 Aug 2010, Published online: 17 Oct 2011
 

Abstract

In this study, the as-synthesized rutile nano-TiO2 powders were heated in hydrogen or nitrogen atmosphere at different temperatures. The surface morphology, UV-Vis absorption spectra, and element composition were studied using TEM, UV-Vis spectrometer, and XPS, respectively. The photocatalytic activity of the modified TiO2 samples under visible light irradiation was evaluated by the degradation of methyl orange solution. The results showed that the dispersibility of modified rutile nano-TiO2 powders was improved and its absorption edge was red shift to visible light because the presence of oxygen vacancies changed the energy band structure of rutile TiO2.

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