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Integrated Ferroelectrics
An International Journal
Volume 20, 1998 - Issue 1-4
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Contributed papers

Preparation and properties of single crystals in the system of pb{(Mg1-xZnx)1/3Nb2/3}O3 by flux method

H. Suzuki Department of Materiats Science, Faculty of Engineering, Shizuoka University, Hamamatsu, 432, Japan
,
H. Takase Department of Materiats Science, Faculty of Engineering, Shizuoka University, Hamamatsu, 432, Japan
,
K. Murakami Research Institute of Electronics, Shizuoka University, Hamamatsu, 432, Japan
,
S. Kaneko Department of Materiats Science, Faculty of Engineering, Shizuoka University, Hamamatsu, 432, Japan
,
Y. Kubo Department of Materiats Science, Faculty of Engineering, Shizuoka University, Hamamatsu, 432, Japan
&
F. Imoto Department of Materiats Science, Faculty of Engineering, Shizuoka University, Hamamatsu, 432, Japan
Pages 259-260 | Published online: 27 Sep 2006
 
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Abstract

Single crystals of perovskite type Pb{(Mg1-xZnx)1/3Nb2/3}O3 (PMZN) solid solutions were prepared by a PbO flux method with excess additions of MgO and/or ZnO. The optimum condition to obtain relatively large single crystals in this system was determined. As a result, rapid quenching is essential for the formation of the perovskite PMZN single crystals, which showed the successive change of the lattice parameters. However, the lattice parameter did not change in proportion to the bath composition (Fig. 1). These results exhibited the difficulty to prepare the single crystals with relatively high content ZnO more than 40%.

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