Synthesis and Molecular Structure of the Amido-Bridged Dinuclear Rhodium Complex [CpRh{μ₂-(NH)₂C₁₀H₆-2,3}(μ₂-Cl)RhCp][PF₆] (Cp* = η⁵-C₅Me₅)

Hiroyuki Matsuzaka Department Of Chemistry, Graduate School of Science, Tokyo Metropolitan University, Minami-osawa, Hachioji, Tokyo, 192-0397, Japan

Teruo Kamura Department Of Chemistry, Graduate School of Science, Tokyo Metropolitan University, Minami-osawa, Hachioji, Tokyo, 192-0397, Japan

Ko Ariga Department Of Chemistry, Graduate School of Science, Tokyo Metropolitan University, Minami-osawa, Hachioji, Tokyo, 192-0397, Japan

Takashi Okubo Department Of Chemistry, Graduate School of Science, Tokyo Metropolitan University, Minami-osawa, Hachioji, Tokyo, 192-0397, Japan

Tomohiko Ishii Department Of Chemistry, Graduate School of Science, Tokyo Metropolitan University, Minami-osawa, Hachioji, Tokyo, 192-0397, Japan

Masahiro Yamashita Department Of Chemistry, Graduate School of Science, Tokyo Metropolitan University, Minami-osawa, Hachioji, Tokyo, 192-0397, Japan

Mitsuru Kondo Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Kyoto, 606-8501, Japan

Susumu Kitagawa Department Of Chemistry, Graduate School of Science, Tokyo Metropolitan University, Minami-osawa, Hachioji, Tokyo, 192-0397, Japan

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Abstract

Reaction of [Cp*RhCl₂]₂ (1) with (LiNH)₂C₁₀H₆-2,3 gives the mononuclear species Cp*Rh(NH)₂C₁₀H₆-2,3 (3), which is selectively converted to the amido-bridged dinuclear Rh(III) complex [Cp*Rh{μ₂-(NH)₂C₁₀H₆-2,3}(μ₂-Cl)RhCp*]PF₆ (4; Cp* = η⁵-C₅Me₅) upon treatment with 1/AgPF₆ in acetone. The molecular structure of 4 has been determined by X-ray crystallography.

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Synthesis and Molecular Structure of the Amido-Bridged Dinuclear Rhodium Complex [CpRh{μ₂-(NH)₂C₁₀H₆-2,3}(μ₂-Cl)RhCp][PF₆] (Cp* = η⁵-C₅Me₅)

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Synthesis and Molecular Structure of the Amido-Bridged Dinuclear Rhodium Complex [Cp*Rh{μ2-(NH)2C10H6-2,3}(μ2-Cl)RhCp*][PF6] (Cp* = η5-C5Me5)

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Synthesis and Molecular Structure of the Amido-Bridged Dinuclear Rhodium Complex [CpRh{μ₂-(NH)₂C₁₀H₆-2,3}(μ₂-Cl)RhCp][PF₆] (Cp* = η⁵-C₅Me₅)