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Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals Volume 342, 2000 - Issue 1
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Original Articles

Measurement of Association Constants in Metal Orotate Complexes by 1H NMR Spectroscopy: the Metal Substituent Effect on Triple Hydrogen Bonding Ability

Xingling Xu Department of Chemistry, Imperial College of Science, Technology and Medicine, South Kensington, London, SW7 2AY, UK
,
Michael Hynes Department of Chemistry, National University of Ireland, Galway, Ireland
,
Stuart L. James Department of Chemistry, Imperial College of Science, Technology and Medicine, South Kensington, London, SW7 2AY, UK
,
D. Michael Department of Chemistry, Imperial College of Science, Technology and Medicine, South Kensington, London, SW7 2AY, UK; The Principal′s Lodgings, St. Edmund Hall, Queens Lane, Oxford, OX1 4AR E-mail: [email protected]
&
P. Mingos Department of Chemistry, Imperial College of Science, Technology and Medicine, South Kensington, London, SW7 2AY, UK; The Principal′s Lodgings, St. Edmund Hall, Queens Lane, Oxford, OX1 4AR E-mail: [email protected]
Pages 15-27 | Published online: 24 Sep 2006
 
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Abstract

The metal substituent effect on complementary triple hydrogen bonding pairs was investigated by 1H NMR spectroscopy. The results demonstrated that the metal ion reduced the hydrogen bonding ability of the ADA complex [NBu4][Rh(cod)(orotate)] with 2,6-diaminopyridine.

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