Synthesis and Magnetic Property of Adducts of Ruthenium(II,III) Pivalate with 9,10-Anthraquinone

Daisuke Yoshioka Department of Chemistry, School of Science, Kwansei Gakuin University, Uegahara, Nishinomiya, 662-8501, Japan

Makoto Handa Department of Material Science, Interdisciplinary Faculty of Science and Engineering, Shimane University, Nishikawatsu, Matsue, 690-8504, Japan

Hiroshi Azuma Department of Chemistry, School of Science, Kwansei Gakuin University, Uegahara, Nishinomiya, 662-8501, Japan

Masahiro Mikuriya Department of Chemistry, School of Science, Kwansei Gakuin University, Uegahara, Nishinomiya, 662-8501, Japan

Ichiro Hiromitsu Department of Material Science, Interdisciplinary Faculty of Science and Engineering, Shimane University, Nishikawatsu, Matsue, 690-8504, Japan

Kuninobu Kasuga Department of Material Science, Interdisciplinary Faculty of Science and Engineering, Shimane University, Nishikawatsu, Matsue, 690-8504, Japan

Abstract

Reaction of tetrakis(pivalato)diruthenium(II,III) cation dimer and 9,10-anthraquinone (aq) gave two kinds of adducts, [{Ru₂(piv)₄(H₂O)}₂(aq)]-(BF₄)₂ (1) (pivH = pivalic acid) and [Ru₂(piv)₄(aq)]_n (2), depending on the condition. Very weak antiferromagnetic interaction was observed for 1. The X-ray crystal structure of 2 shows an one-dimensional chain structure.

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Synthesis and Magnetic Property of Adducts of Ruthenium(II,III) Pivalate with 9,10-Anthraquinone

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Synthesis and Magnetic Property of Adducts of Ruthenium(II,III) Pivalate with 9,10-Anthraquinone

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