Crystal Structure and Magnetic Property of Cobalt(II) Assembled Compound, {[Co(CA)(bipym)](H₂O)₂}_n (H₂CA = chloranilic acid, bipym = 2,2′-bipyrimidine)

M. K. Kabir Department of Chemistry, Shizuoka University, 836 Oya, Shizuoka, 422-8529, Japan

S. Kawata Department of Chemistry, Shizuoka University, 836 Oya, Shizuoka, 422-8529, Japan

K. Adachi Department of Chemistry, Shizuoka University, 836 Oya, Shizuoka, 422-8529, Japan

H. Kumagai Institute for Molecular Science, Myoudaiji, Okazaki, Aichi, 444-8585, Japan

S. Kitagawa Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Yoshida, Sakyo-ku, Kyoto, 606-8501, Japan

Abstract

Cobalt(II) assembled complex compound, {[Co(CA)(bipym)](H₂O)₂}_n(H₂CA = chloranilie acid, bipym = 2,2′-bipyrimidine) (1) has been synthesized and structurally characterized by single-crystal X-ray diffraction. Compound 1 crystalizes in the monoclinic, space group C2/c(#15), with a = 16.652(4) Å, b = 11.163(3) Å, c = 10.081(3) Å, β = 116.12(2)°, V = 1682.4(7) Å³, Z = 4. The bipym ligands bridge the cobalt centers in bis-bidentate fashion and make zigzag chains. The chains form layer structures by stacking interaction and hydrogen bonding interaction with the help of interstitial water molecules. The temperature dependence of the magnetic susceptibility of 1 shows intramolecular antiferromagnetic interaction with θ = - 39.7 K.

Key Words:

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Crystal Structure and Magnetic Property of Cobalt(II) Assembled Compound, {[Co(CA)(bipym)](H₂O)₂}_n (H₂CA = chloranilic acid, bipym = 2,2′-bipyrimidine)

Related Research Data

Information for

Open access

Opportunities

Help and information

Crystal Structure and Magnetic Property of Cobalt(II) Assembled Compound, {[Co(CA)(bipym)](H2O)2}n (H2CA = chloranilic acid, bipym = 2,2′-bipyrimidine)

Abstract

Reprints and Corporate Permissions

Academic Permissions

Related Research Data

Related research

To cite this article:

Download citation

Information for

Open access

Opportunities

Help and information

Keep up to date

Your download is now in progress and you may close this window

Login or register to access this feature

Crystal Structure and Magnetic Property of Cobalt(II) Assembled Compound, {[Co(CA)(bipym)](H₂O)₂}_n (H₂CA = chloranilic acid, bipym = 2,2′-bipyrimidine)