Synthesis and Crystal Structure of [Cu(N-salicylidene-3-aminopyridine)₂]_n Constructed from Unsymmetric Bridging Ligand with Two Dissimilar Metal-Binding Sites

Shin-Ichiro Noro Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, 1-1 Minamiohsawa, Hachioji-shi, Tokyo, 192-0397, Japan

Mitsuru Kondo Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Yoshida, Sakyo-ku, Kyoto, 606-8501, Japan

Susumu Kitagawa Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Yoshida, Sakyo-ku, Kyoto, 606-8501, Japan

Tomohiko Ishii Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, 1-1 Minamiohsawa, Hachioji-shi, Tokyo, 192-0397, Japan

Hiroyuki Matsuzaka Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, 1-1 Minamiohsawa, Hachioji-shi, Tokyo, 192-0397, Japan

Masahiro Yamashita Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, 1-1 Minamiohsawa, Hachioji-shi, Tokyo, 192-0397, Japan

Abstract

Synthesis and characterization of novel coordination polymer, [Cu(salapy)₂] _n (Hsalapy = N-salicylidene-3-aminopyridine), having the 2-D thick layer structure is reported.

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Synthesis and Crystal Structure of [Cu(N-salicylidene-3-aminopyridine)₂]_n Constructed from Unsymmetric Bridging Ligand with Two Dissimilar Metal-Binding Sites

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Synthesis and Crystal Structure of [Cu(N-salicylidene-3-aminopyridine)2]n Constructed from Unsymmetric Bridging Ligand with Two Dissimilar Metal-Binding Sites

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Synthesis and Crystal Structure of [Cu(N-salicylidene-3-aminopyridine)₂]_n Constructed from Unsymmetric Bridging Ligand with Two Dissimilar Metal-Binding Sites