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Liquid Crystals

Discotic Liquid Crystals of Transition Metal Complexes 151: Dimer Discotic Rectangular Ordered Columnar Mesophase in Bis(p-n-hexadecylbiphenylbutane-1,3- dionato)copper(II) Complex

, , , , &
Pages 143-149 | Received 15 Apr 1991, Published online: 24 Sep 2006
 

Abstract

The bis(p-n-hexadecylbiphenylbutane-1,3-dionato)copper(II) complex shows a dimer discotic rectangular ordered columnar (D ro ) mesophase as the same case as the hexadecyloxy derivative. The lattice constants of the two-dimensional rectangular system are a = 47.74 Å. b = 16.8 Å. It was shown that the oxygen atoms in the peripheral alkoxy chains have no effect on the formation of the dimers.

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