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Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals Volume 231, 1993 - Issue 1
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Liquid Crystals

Organometallic Ferroelectric Liquid Crystals. II. Syntheses, Characterization and Mesogenic Properties of Amino-Acid Chelated-Palladated Azine, Azo and Imine Mononuclear Complexes

De-Jian Huang Chengdu Institute of Organic Chemistry, Academia Sinica, 610015, Chengdu, China
,
Nu-Yun Xiong Chengdu Institute of Organic Chemistry, Academia Sinica, 610015, Chengdu, China
,
Jun Yang Chengdu Institute of Organic Chemistry, Academia Sinica, 610015, Chengdu, China
,
Shu-Mei Wang Chengdu Institute of Organic Chemistry, Academia Sinica, 610015, Chengdu, China
,
Guang-Nian Li Chengdu Institute of Organic Chemistry, Academia Sinica, 610015, Chengdu, China
&
Liang-Fu Zhang Chengdu Institute of Organic Chemistry, Academia Sinica, 610015, Chengdu, China
Pages 191-198 | Received 03 Aug 1992, Accepted 30 Oct 1992, Published online: 24 Sep 2006
 
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Abstract

Six mononuclear ortho-palladated complexes containing amino-acid chelate ligands and azine or azo, imine ligands have been synthesized and characterized by elemental analysis, IR, 1H NMR and 13C NMR. Their thermotropic behaviors and mesogenic properties were studied. The relation between mesogenic properties and molecular structures of complexes were also discussed. As a result, three novel organometallic ferroelectric liquid crystals were found.

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