Solid-State Photosolvolysis of Clathrate Crystals Including Ethanol as a Guest Component

Naoto Hayashi Department of Chemistry, College of Arts and Sciences, The University of Tokyo, Komaba, Meguro-ku, Tokyo, 153, Japan

Yasuhiro Mazaki Department of Chemistry, College of Arts and Sciences, The University of Tokyo, Komaba, Meguro-ku, Tokyo, 153, Japan

Keiji Kobayashi Department of Chemistry, College of Arts and Sciences, The University of Tokyo, Komaba, Meguro-ku, Tokyo, 153, Japan

Abstract

A simple bimolecular photosubstitution at a saturated carbon atom of the host by the guest molecule has been observed in the clathrate crystals which are composed of 9-fluorenyl substituted thienothiophenes as a host component and include ethanol as a guest species. Based on the X-ray analyses, topochemical characteristics of this novel solid-state photosolvolysis are discussed.

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Solid-State Photosolvolysis of Clathrate Crystals Including Ethanol as a Guest Component

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Solid-State Photosolvolysis of Clathrate Crystals Including Ethanol as a Guest Component

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