Photoinduced Processes in Dinuclear Complexes Containing Rigid Bridging Ligands

Luisa De Cola Dipartimento di Chimica “G. Ciamician”, Università di Bologna, and Istituto FRAE-CNR, Bologna, Italy

Vincenzo Balzani Dipartimento di Chimica “G. Ciamician”, Università di Bologna, and Istituto FRAE-CNR, Bologna, Italy

Francesco Barigelletti Dipartimento di Chimica “G. Ciamician”, Università di Bologna, and Istituto FRAE-CNR, Bologna, Italy

Lucia Flamigni Dipartimento di Chimica “G. Ciamician”, Università di Bologna, and Istituto FRAE-CNR, Bologna, Italy

Peter Belser Institut für Anorganische Chemie, Universität, Freiburg, Switzerland

Alex Von Zelewsky Institut für Anorganische Chemie, Universität, Freiburg, Switzerland

Michael Frank Institut für Organische Chemie und Biochemie, Universität, Bonn, Germany

Fritz Vögtle Institut für Organische Chemie und Biochemie, Universität, Bonn, Germany

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Abstract

We report the synthesis and the properties of some dinuclear ruthenium and/or osmium complexes bridged by rigid ligands. We focus on the nature of the bridging ligand and on its effect on the electrochemical, structural, and photophysical behavior of the complexes. Intercomponent energy and electron transfer processes are discussed.

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Photoinduced Processes in Dinuclear Complexes Containing Rigid Bridging Ligands

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Photoinduced Processes in Dinuclear Complexes Containing Rigid Bridging Ligands

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