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Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals Volume 274, 1995 - Issue 1
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Original Articles

First Examples of Long Range Magnetic Ordering of Structurally Characterized Pentachloroferrate III Di-Anions: FeCl52-, and Its Methanol and Aquo Adducts

W. M. Reiff Department of Chemistry, Northeastern University, Boston, MA, 02125, USA
&
B. D. James Department of Chemistry, Latrobe University, Bundoora, Victoria, Australia, 3083
Pages 41-49 | Published online: 24 Sep 2006
 
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Abstract

A. C. susceptibility and iron-57 Mossbauer spectroscopy measurements are used to investigate the first examples of cooperative magnetic ordering phenomena for FeCl3 2- anions and the related methanol and aquo adducts. Depending on the counter cation and/or solvate identity examples of uncanted antiferromagnetic and canted (weakly ferromagnetic) three dimensional order are observed with critical temperatures - 7K.

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