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Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals Volume 274, 1995 - Issue 1
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Original Articles

New Insulating Layered Network 3D-Ferromagnets Composed of the Divalent Metal Perrhenates: Fe(ReO4)2, Co(ReO4)2 and Ni(ReO4)2

W. M. Reiff Department of Chemistry, Northeastern University, Boston, Mass, 02115; NSF Division of Materials Research
,
B. C. Dodrill Lakeshore Cryotronics, Inc, Westerville, Ohio, 43081
&
C. C. Torardi DuPont Co., Central Research & Development, Wilmington, DE, 19880-0356
Pages 137-143 | Published online: 24 Sep 2006
 
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Abstract

A variety of a.c. and d.c. magnetrometry data as well as iron-57 Mossbauer spectra show that the structurally layered divalent metal perrhenates: M(ReO4)2 (M = Ni, Fe, Co) have three dimensional ferromagnetic ground states with Curie temperatures of 12.5K, 8.5K and 4.7K respectively. The nickel compound exhibits a substantial coercivity (∼ 0.26T) at 4.2K.

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