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Original Articles

A New Maximum Entropy Conformational Analysis of Biphenyl in Liquid Crystal Solution

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Pages 245-253 | Published online: 24 Sep 2006
 

Abstract

We use the maximum entropy internal order (MEIO) method to reanalyze published 1HNMR dipolar couplings for biphenyl dissolved in nematic solvents allowing for geometry variations with dihedral angle ø. We find that all present experimental data are consistent with similar conformational distributions with a maximum at ø = 34–35°. Little rotational-conformational coupling has been found.

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