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Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals Volume 276, 1996 - Issue 1-2
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Original Articles

Fractional Enclathration-Crystallisation Behaviour of the Zeolite-Mimetic [Onium•xG]•[Cd3(CN)7] 3D Hosts for Aromatic Guests Benzene, Toluene, Ethylbenzene and Xylene Isomers

Chong-Hyeak Kim Department of Chemistry, College of Arts and Sciences, The University of Tokyo, Komaba, Meguro, Tokyo, 153, Japan
,
Shin-Ichi Nishkiori Department of Chemistry, College of Arts and Sciences, The University of Tokyo, Komaba, Meguro, Tokyo, 153, Japan
&
Toschitake Iwamoto Department of Chemistry, College of Arts and Sciences, The University of Tokyo, Komaba, Meguro, Tokyo, 153, Japan
Pages 13-18 | Published online: 04 Oct 2006
 
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Abstract

Inclusion selectivity of [onium•xG]•[Cd3(CN)7] (onium = NMe4 + or SMe3 +) clathrates were investigated for C6H6 (B), PhMe (T), ortho (O), meta (M) and para (P) isomers of C6H4Me2 (X) and PhEt (E) as G upon the enclathration-crystallisation processes of the respective mixed guest clathrates from the binary, ternary, quaternary and quinary mixtures of B, T, X and E. The order of preference in the NMe4 +-host is T>B>P≫M>O and E>P≫M>O; in the SMe3 +- host P>T>B≫M>O and P>E≫M>O.

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