Intelligent Sugar Complexes

Shigenobu Yano Department of Chemistry, Nara Women's University, Nara, Nara, 630, Japan

Masako Nakagoshi Department of Chemistry, Nara Women's University, Nara, Nara, 630, Japan

Akemi Teratani Department of Chemistry, Nara Women's University, Nara, Nara, 630, Japan

Masako Kato Department of Chemistry, Nara Women's University, Nara, Nara, 630, Japan

Tomoaki Tanase Department of Chemistry, Toho University, Funabashi, Chiba, 274, Japan

Yasuhiro Yamamoto Department of Chemistry, Toho University, Funabashi, Chiba, 274, Japan

Hidehiro Uekusa Department of Chemistry, Tokyo Institute of Technology, Meguro, Tokyo, 152, Japan

Yuji Ohashi Department of Chemistry, Tokyo Institute of Technology, Meguro, Tokyo, 152, Japan

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Abstract

The structure of [Co(L-Rha)₃-mn)]Br₂.2CH₃OH, where (Rhah-tren is tris(N-rhamnosyl-2-aminoethyl)amine, was elucidated by X-ray crystallography, which confirmed the unprecedented configurational inversion of [Co((Rha)₃-tren)]²⁺, around the metal center reversibly by an addition and a removal of sulfate.

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Intelligent Sugar Complexes

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