Induction and Stabilization of Smectic Phases in Amphiphilic Hydrogen-Bond Complexes

R. V. Talroze Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sci., Leninsky pr. 29, 117912, Moscow, Russia

G. A. Shandryuk Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sci., Leninsky pr. 29, 117912, Moscow, Russia

S. A. Kuptsov Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sci., Leninsky pr. 29, 117912, Moscow, Russia

V. S. Bezborodov Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sci., Leninsky pr. 29, 117912, Moscow, Russia

N. A. Platé Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sci., Leninsky pr. 29, 117912, Moscow, Russia

Abstract

Hydrogen-bond complexes of dicarboxylic malonic and glutaric acids with β-N-dimethylamino-4-dodecyloxypropiophenone are studied by means' of FT-IR spectroscopy, optical microscopy, DSC and X-ray analysis. The formation of a thermotropic SA phase is proved and the model of the layered structure formation is given. The mesomorphic behavior of complexes is discussed in terms of amphiphilic systems.

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Induction and Stabilization of Smectic Phases in Amphiphilic Hydrogen-Bond Complexes

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Induction and Stabilization of Smectic Phases in Amphiphilic Hydrogen-Bond Complexes

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