Synthesis and Properties of Mono- and Dications of 1,1 -Diferrocen Yleth Ylenes

Masahiko Iyoda Department of Chemistry, Faculty of Science, Tokyo Metropolitan University, Hachioji, Tokyo, 192-03, Japan

Toshitaka Okabe Department of Chemistry, Faculty of Science, Tokyo Metropolitan University, Hachioji, Tokyo, 192-03, Japan

Terumasa Kondo Department of Chemistry, Faculty of Science, Tokyo Metropolitan University, Hachioji, Tokyo, 192-03, Japan

Shigeru Sasaki Department of Chemistry, Faculty of Science, Tokyo Metropolitan University, Hachioji, Tokyo, 192-03, Japan

Haruo Matsuyama Department of Chemistry, Faculty of Science, Tokyo Metropolitan University, Hachioji, Tokyo, 192-03, Japan

Yoshiyuki Kuwatani Department of Chemistry, Faculty of Science, Tokyo Metropolitan University, Hachioji, Tokyo, 192-03, Japan

Motomi Katada Radioisotope Research Center, Tokyo Metropolitan University, Hachioji, Tokyo, 192-03, Japan

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Abstract

1,1-Diferrocenylethylenes have been synthesized efficiently by palladium-catalyzed cross-coupling reaction. The interaction of the two ferrocene units has been investigated in the neutral, monocationic and dicationic states using spectroscopic analyses.

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Synthesis and Properties of Mono- and Dications of 1,1 -Diferrocen Yleth Ylenes

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Synthesis and Properties of Mono- and Dications of 1,1 -Diferrocen Yleth Ylenes

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