Energy Transfer From Tris(2,2′-Bipyridine)Ruthenium(II) or Tris(2,2′-Bipyridine)Osmium(II) To Hexacyanochromate(III) in a Pure Crystal of Double Complex Salt

Takuhiro Otsuka Department of Chemistry, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo, 152, Japan

Naoto Takahashi Department of Chemistry, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo, 152, Japan

Youkoh Kaizu Department of Chemistry, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo, 152, Japan

Abstract

It is clarified by performing X-ray structure analysis that the crystal structure of [Ru(bpy)₃]₂[Cr(CN)₆]CI·8H₂O (bpy = 2,2′-bipyridine) is the same as that of [Os(bpy)₃]₂[Cr(CN)₆]Cl·8H₂O. The difference of energy transfer rate from [M(bpy)₃]²⁺ (M=Ru²⁺ or Os²⁺) to [Cr(CN)₆]^3- in pure crystals of double complex salts ([M(bpy)₃]₂[Cr(CN)₆]Cl·8H₂O) is discussed in terms of the spectroscopic characters and lifetimes of the salts.

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Energy Transfer From Tris(2,2′-Bipyridine)Ruthenium(II) or Tris(2,2′-Bipyridine)Osmium(II) To Hexacyanochromate(III) in a Pure Crystal of Double Complex Salt

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Energy Transfer From Tris(2,2′-Bipyridine)Ruthenium(II) or Tris(2,2′-Bipyridine)Osmium(II) To Hexacyanochromate(III) in a Pure Crystal of Double Complex Salt

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