Models for Charged Organic High-Spin Systems; Synthesis and Cyclic Voltammetry of One- and Two-Dimensional Diarylaminobenzenes

Wasafumi Yano Department of Chemistry Faculty of Science, Osaka City University, Sumiyoshi-ku, Osaka, 558, Japan

Mutsuo Furuichi Department of Chemistry Faculty of Science, Osaka City University, Sumiyoshi-ku, Osaka, 558, Japan

Kazunobu Sato Department of Chemistry Faculty of Science, Osaka City University, Sumiyoshi-ku, Osaka, 558, Japan

Daisuke Shiomi Department of Material Science, Faculty of Science, Osaka City University, Sumiyoshi-ku, Osaka, 558, Japan

Akio Ichimura Department of Chemistry Faculty of Science, Osaka City University, Sumiyoshi-ku, Osaka, 558, Japan

Kyo Abe Department of Chemistry Faculty of Science, Osaka City University, Sumiyoshi-ku, Osaka, 558, Japan

Takeji Takui Department of Chemistry Faculty of Science, Osaka City University, Sumiyoshi-ku, Osaka, 558, Japan

Koichi Itoh Department of Material Science, Faculty of Science, Osaka City University, Sumiyoshi-ku, Osaka, 558, Japan

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Abstract

A series of 1,3-di(diarylamino)benzenes (DABs) and 1,3,5-tris(diarylamino) benzenes (TABs) were synthesized as model precursors for polycationic πconjugated high-spin systems. CV measurement at low temperature showed that the chemical stability in solution of mono- and polycationic oxidation states of the various DABs and TABs derivatives depend on their structures. Correlation between the chemical stability of these cations and their molecular structure is discussed.

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Models for Charged Organic High-Spin Systems; Synthesis and Cyclic Voltammetry of One- and Two-Dimensional Diarylaminobenzenes

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Models for Charged Organic High-Spin Systems; Synthesis and Cyclic Voltammetry of One- and Two-Dimensional Diarylaminobenzenes

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