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Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals Volume 334, 1999 - Issue 1
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Original Articles

Electronic Properties of Bisporphyrin Biradical Dications

David A. Shultz Department of Chemistry, North Carolina State University, Raleigh, NC, 27695-8204
,
Hyoyoung Lee Department of Chemistry, North Carolina State University, Raleigh, NC, 27695-8204
,
Kevin P. Gwaltney Department of Chemistry, North Carolina State University, Raleigh, NC, 27695-8204
&
Kay A. Sandberg Department of Chemistry, North Carolina State University, Raleigh, NC, 27695-8204
Pages 459-467 | Published online: 24 Sep 2006
 
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Abstract

We describe the oxidations of bisporphyrins 1-Zn2 - 6-Zn2 , and present EPR spectra of chemically oxidized species that are consistent with exchange-coupled biradicals.

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