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Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals Volume 334, 1999 - Issue 1
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Original Articles

New Molecule-Based Magnets: From Hexacyano to Octacyanometalates

Raquel Garde Chimie Inorganique et Matériaux Moleculaires, E.S.A. C.N.R.S., 7071, 4 Place Jussieu, Université P. et M. Curie, 75252, Paris, France
,
Cedric Desplanches Chimie Inorganique et Matériaux Moleculaires, E.S.A. C.N.R.S., 7071, 4 Place Jussieu, Université P. et M. Curie, 75252, Paris, France
,
Anne Bleuzen Chimie Inorganique et Matériaux Moleculaires, E.S.A. C.N.R.S., 7071, 4 Place Jussieu, Université P. et M. Curie, 75252, Paris, France
,
Pierre Veillet Institut d'Electronique Fondamentale, Université Paris-Sud, Orsay, France
&
Michel Verdaguer Chimie Inorganique et Matériaux Moleculaires, E.S.A. C.N.R.S., 7071, 4 Place Jussieu, Université P. et M. Curie, 75252, Paris, France
Pages 587-595 | Published online: 24 Sep 2006
 
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Abstract

Prussian blue molecule-based magnets can be designed to exhibit various magnetic properties. One of them based on chromicyanide and vanadium is a magnet at room temperature. Its properties are very sensitive to the synthetic reaction conditions, solvent effects and counterions which can be used to tune the Tc. To study the interaction between nearest metallic neighbours we explore also the influence of diffuse and high energy magnetic orbitals, i.e. 4d or 5d metallic orbitals. Two derivatives of [Wv(CN)8]3- are presented.

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Related Research Data

Cyano-bridged gadolinium(iii)-tungstate(v) bimetallic assembly with a one-dimensional chain structure
Source: Royal Society of Chemistry (RSC)
Poly[[diaquadeca-μ -cyanido-κ : -hexacyanido-κ -bis(μ -5-methylpyrimidine-κ : ′)bis(5-methylpyrimidine-κ )tricopper(II)ditungstate(V)] dihydrate]
Source: (:unav)
Observation of an Iron(II) Spin-Crossover in an Iron Octacyanoniobate-Based Magnet
Source: Wiley
Studies of Er( )–W( ) compounds showing nonlinear optical activity and single-molecule magnetic properties
Source: Royal Society of Chemistry (RSC)
Poly[[diaquadeca-μ-cyanido-hexacyanidobis(4-cyanopyridine)di-μ-pyrimidine-tricopper(II)ditungsten(V)] dihydrate]
Source: International Union of Crystallography (IUCr)
An Unusual (10,3)-d MOF Material with Nanoscale Helical Cavities and Multifunctionality
Source: Wiley
Poly[aquahexabenzimidazoleocta-μ-cyanido-octacyanidotricopper(II)ditungstate(V)]
Source: International Union of Crystallography (IUCr)
Observation of an Iron(II) Spin-Crossover in an Iron Octacyanoniobate-Based Magnet
Source: Wiley
Two-dimensional metamagnet composed of cyano-bridged CuII-WV bimetallic assembly.
Source: (:unav)
Magnetic Prussian Blue Analogs
Source: Wiley-VCH Verlag GmbH & Co. KGaA

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