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Low-Dimensional Solids and Molecular Crystals

Organic Solid State Reactivity: Reaction between 8-Hydroxyquinoline and Nitrophenols

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Pages 269-279 | Received 19 Jun 1998, Published online: 24 Sep 2006
 

Abstract

8-Hydroxyquinoline reacts with 2,4-dinitro-and 2,4,6-trinitro phenols in solid state and the reactivity increased with the increase of number of nitro groups in the phenols. Phenol and m-nitro phenol formed only eutectic mixtures with 8-hydroxyquinoline. The reactivity is related with the symmetry and size of the diffusing molecules. The products obtained from solution and solid state reaction are found to be chemically identical.

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