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Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals Volume 331, 1999 - Issue 1
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SECTION VII: APPLICATIONS

Side-On Fixed Liquid Crystalline Polymers: New Stationary Phases for High Performance Liquid Chromatography

Isabelle Terrien Ecole Nationale Supérieure de Chimie et de Physique, Av, Pey Berland, B.P. 108, F-33402, Talence, France; Centre de Recherche Paul Pascal, Université de Bordeaux I, Av. du Dr. Schweitzer, F-33600, Pessac, France
,
Guy Félix Ecole Nationale Supérieure de Chimie et de Physique, Av, Pey Berland, B.P. 108, F-33402, Talence, France
,
Michel Laguerre Centre de Recherche Paul Pascal, Université de Bordeaux I, Av. du Dr. Schweitzer, F-33600, Pessac, France
,
Marie-France Achard Centre de Recherche Paul Pascal, Université de Bordeaux I, Av. du Dr. Schweitzer, F-33600, Pessac, France
&
Francis Hardouin Centre de Recherche Paul Pascal, Université de Bordeaux I, Av. du Dr. Schweitzer, F-33600, Pessac, France
Pages 431-438 | Published online: 04 Oct 2006
 
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Abstract

New stationary phases are obtained by coating on a silica support liquid crystalline polysiloxanes with mesogenic side groups laterally attached to the polymer backbone through the flexible spacer. They show very good chromatographic performances in HPLC for the separation of polycyclic aromatic hydrocarbons. Solute/mesogenic group interactions are evaluated through molecular mechanics calculations and correlated to the chromatographic results.

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