Oxidation of Styrene with Molecular Oxygen Catalyzed by Polymer‐Supported O‐Aminobenzoic Acid Salicylaldehyde Schiff‐Base Copper(II) Complex

Yue Chang Department of Chemistry, Northwest Normal University, Lanzhou, P.R. China; Gansu Key Laboratory of Polymer Materials, Lanzhou, P.R. ChinaCorrespondence[email protected]

Fei Zha Department of Chemistry, Northwest Normal University, Lanzhou, P.R. China; Gansu Key Laboratory of Polymer Materials, Lanzhou, P.R. China

Bitao Su Department of Chemistry, Northwest Normal University, Lanzhou, P.R. China; Gansu Key Laboratory of Polymer Materials, Lanzhou, P.R. China

Yunpu Wang Department of Chemistry, Northwest Normal University, Lanzhou, P.R. China; Gansu Key Laboratory of Polymer Materials, Lanzhou, P.R. China

Abstract

Schiff‐base complexes of copper supported on chloromethylated polystyrene as a catalyst have been studied in the oxidation of styrene with molecular oxygen. The main products are benzaldehyde and the epoxide of styrene. Compared with the unsupported copper complex, the polymer supported complex has more effective catalytic activity, and could be easily separated and reused. The influences of reaction temperature and the amount of catalyst have also been investigated.

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Oxidation of Styrene with Molecular Oxygen Catalyzed by Polymer‐Supported O‐Aminobenzoic Acid Salicylaldehyde Schiff‐Base Copper(II) Complex

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Oxidation of Styrene with Molecular Oxygen Catalyzed by Polymer‐Supported O‐Aminobenzoic Acid Salicylaldehyde Schiff‐Base Copper(II) Complex

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