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Original Articles

Synthesis and Characterization of Polyindole/Poly(vinyl acetate) Conducting Composites

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Pages 205-211 | Received 01 Aug 2007, Accepted 01 Sep 2007, Published online: 30 Jan 2008
 

Composites of a polyindole (PIN) and poly(vinyl acetate) (PVAc) were prepared chemically using FeCl3 as an oxidant agent in anhydrous media. The composite compositions were altered by varying the indole monomer during preparation. The composites were characterized by FTIR and UV‐visible spectroscopies, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), scanning electron microscopy (SEM), stress‐strain experiments and conductivity measurements. Moreover, the film of PVAc and PIN/PVAc composites were prepared by casting on glass Petri dishes to examine their stress‐strain properties. PIN/PVAc composites are thermally more stable than PIN. It was found that the conductivities of PIN/PVAc composites depend on the indole content in the composites.

5 Acknowledgements

This study was supported by the state planning organization of Turkey (Grant No: 2001K120590). The authors thank Dr Metin Gürü for TGA, Yüksel Akyüz for Stress‐Strain measurements, and to Erdem Yaşar for SEM.

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