The Influence of Pore Structures and Degree of Crosslinking on Catalytic Properties of Aminomethyl Polystyrene Resins Supported Dendritic Sn Complexes

Jiaqin Wang Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China

Renren Wang Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China

Zhe Zhang Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China

Cuilin Li Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China

Zhiwang Yang Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China

Ziqiang Lei Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, ChinaCorrespondence[email protected]

Seven different aminomethyl polystyrene resins supported dendritic Sn complexes were prepared by solid phase synthesis methodology. All the synthesized complexes show promising catalytic activities for the Baeyer‐Villiger oxidation of ketones with hydrogen peroxide and affording the corresponding lactones or esters. The influence of different pore structures and the degree of crosslinking of the aminomethyl polystyrene resins on catalytic properties of the supported dendritic Sn complexes were well discussed.

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5 Acknowledgments

The authors acknowledge support by the National Natural Science Foundation of China (20174031 and 20474052), Specialized Research Fund for the Doctoral Program of Higher Education (20050736001) and Key Laboratory of Eco‐Environment‐Related Polymer Materials

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The Influence of Pore Structures and Degree of Crosslinking on Catalytic Properties of Aminomethyl Polystyrene Resins Supported Dendritic Sn Complexes

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The Influence of Pore Structures and Degree of Crosslinking on Catalytic Properties of Aminomethyl Polystyrene Resins Supported Dendritic Sn Complexes

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