Removal of Cd(II) and Cu(II) ions from aqueous solutions using tannin-phenolic polymer immobilized on cellulose

Abstract

Tannin was crosslinked with paraformaldehyde to prepare tannin-phenolic polymer(TP), TP immobilized on cellulose (TPPC) was prepared by the cross-linking reaction of TP and cellulose with epichlorohydrin as crosslinking agent. Tannin was crosslinked prior to being immobilized on cellulose, which could increase the effective phenolic hydroxyl content in cellulose skeleton and improve the adsorption property of TPPC for metal ions. The maximum adsorption capacity of TPPC for Cd(II) and Cu(II) ions were 80.11 mg/g and 55.97 mg/g, respectively. The adsorption equilibrium data for the metal solutions fitted the Langmuir model well. The adsorption rate data fitted well to a Pseudo-second-order model. The TPPC has potential application value in the field of metal wastewater treatment.

Keywords:

• Cellulose
• tannin
• adsorption
• polymer
• kinetics

Additional information

Funding

This research was financially supported by National Natural Science Fund of China (31760196) and the collaborative innovation center of manganese-Zinc-Vanadium industrial technology of postgraduate project of Jishou University (2017mzvg004).