Structure/Permeability and Permselectivity Relationship of Polyetherimides from 1,4-Bis(3,4-Dicarboxyphenoxy) Benzene Dianhydride. III

Abstract

Gas permeability coefficients of a series of aromatic polyetherimides prepared from 1,4-bis(3,4-dicarboxyphenoxy) benzene dianhydride (HQDPA) and four (methylene dianiline)s with a methyl side group to H₂, CO₂, O₂, N₂, and CH₄ were measured under 7 atm and within a temperature range from 30 to 150°C. The gas permeabilities and permselectivities of these polymers were compared with those of the HQDPA-based polyetherimides from methylene dianiline (MDA) and isopropylidene dianiline (IPDA). The number and position of the methyl side groups on the benzene rings of the diamine residues strongly affect the gas permeabilities and permselectivities of the HQDPA-based polyetherimides. The gas permeability of the polyetherimide progressively increases with an increase in the number of the methyl side groups. Both the gas permeability and permselectivity of the polyetherimides with methyl side groups are higher than those of HQDPA-MDA. The polyetherimide prepared from 3,3′-dimethyl 4,4′-methylene dianiline (DMMDA1) possesses both higher permeability and permselectivity than the polyetherimides prepared from 2,2′-dimethyl 4,4′-methylene dianiline (DMMDA2). However, two of the polyetherimides prepared from 2,2′,3,3′-tetramethyl 4,4′-methylene dianiline (TMMDA1) or 2,2′,5,5′-tetramethyl 4,4′-methylene dianiline (TMMDA2) possess almost the same gas permeability and permselectivity.